The laboratory study of P441 oil samples separation by using super absorbent polymer from the waste diapers
DOI:
https://doi.org/10.61435/jese.2025.e31Keywords:
Demulsification, Super Absorbent Polymer, Diapers, Waste, PolymerAbstract
The waste diapers, the second largest waste source after plastic, pose environmental challenges due to their slow degradation of 25-50 years. Reprocessing diaper waste, including utilizing Super Absorbent Polymer (SAP), is crucial. SAP's high absorption capacity aids in research for separating crude oil from water, particularly relevant for Indonesian oil wells with aging infrastructure. Emulsions in crude oil, stabilized by natural chemicals, require demulsification to prevent production issues, underscoring the importance of efficient water-oil separation methods. The research experimentally compares oil-in-water emulsion separation using SAP with and without SAP. The study utilizes waste-based ingredients like used diapers, and tests involve centrifuge processes at varying temperatures. SAP's osmotic properties enable high water absorption, impacting demulsification efficiency. This study investigates the impact of temperature on emulsion separation between water and crude oil. Testing at 26°C and 40°C reveals accelerated separation at higher temperatures due to reduced crude oil viscosity. Waste-containing tubes demonstrate better separation, with SAP absorbing water, enhancing separation efficiency. Increasing centrifuge speed and temperature improve oil-water separation, showcasing SAP's effectiveness in waste management processes. Research findings on crude oil-water separation using diaper waste conclude that demulsification is faster at 40°C due to decreased viscosity; with SAP waste, volumes of water are more efficient at 40°C; SAP's hydrophilic nature traps water in the gel network; SAP enhances separation effectiveness compared to non-SAP methods in saline solutions.
References
Abdulredha, M. M., Hussain, S. A., & Abdullah, L. C. (2020). Overview on petroleum emulsions, formation, influence and demulsification treatment techniques. Arabian Journal of Chemistry, 13(1), 3403–3428. https://doi.org/10.1016/j.arabjc.2018.11.014
Aditya, S. M., Samsol, S., Pramadika, H., & Ridaliani, O. (2022). The Use of Sodium Polyacrylate for Oil-Water Demulsification Process. Journal of Earth Energy Science, Engineering, and Technology, 5(1). https://doi.org/10.25105/jeeset.v5i1.9959
Alao, K. T., Alara, O. R., & Abdurahman, N. H. (2021). Trending approaches on demulsification of crude oil in the petroleum industry. Applied Petrochemical Research, 11(3), 281–293. https://doi.org/10.1007/s13203-021-00280-0
Al-Dahhan, W., & Mahmood, S. (2019). Classification of Crude Oils and its Fractions on the Basis of Paraffinic, Naphthenic and Aromatics. Al-Nahrain Journal of Science, 22(3), 35–42. https://doi.org/10.22401/ANJS.22.3.05
Arpit, S., & Jaya, T. (2023). Properties and Applications of Superabsorbent Polymers (S. Arpit & T. Jaya, Eds.). Springer Nature Singapore. https://doi.org/10.1007/978-981-99-1102-8
Bachra, Y., Grouli, A., Damiri, F., Bennamara, A., & Berrada, M. (2020). A new approach for assessing the absorption of disposable baby diapers and superabsorbent polymers: A comparative study. Results in Materials, 8, 100156. https://doi.org/10.1016/j.rinma.2020.100156
Doust, H., & Noble, R. A. (2008). Petroleum systems of Indonesia. Marine and Petroleum Geology, 25(2), 103–129. https://doi.org/10.1016/j.marpetgeo.2007.05.007
Ekebafe, M. O., Ekebafe, L. O., & Maliki, M. (2013). Utilisation of Biochar and Superabsorbent Polymers for Soil Amendment. Science Progress, 96(1), 85–94. https://doi.org/10.3184/003685013X13587941096281
Elgowainy, A., Han, J., Cai, H., Wang, M., Forman, G. S., & DiVita, V. B. (2014). Energy Efficiency and Greenhouse Gas Emission Intensity of Petroleum Products at U.S. Refineries. Environmental Science & Technology, 48(13), 7612–7624. https://doi.org/10.1021/es5010347
Ernyasih, E., Pratiwi, W. E., Andriyani, A., Lusida, N., & Mallongi, A. (2023). Analisis Pengetahuan, Pendidikan Dan Sikap Terhadap Manajemen Popok Sekali Pakai. ENVIRONMENTAL OCCUPATIONAL HEALTH AND SAFETY JOURNAL, 4(1), 75. https://doi.org/10.24853/eohjs.4.1.75-83
Farooq, U., Patil, A., Panjwani, B., & Simonsen, G. (2021). Review on Application of Nanotechnology for Asphaltene Adsorption, Crude Oil Demulsification, and Produced Water Treatment. Energy & Fuels, 35(23), 19191–19210. https://doi.org/10.1021/acs.energyfuels.1c01990
Glinka, M., Jażdżewska, K., Vakh, C., Drążkowska, I., Bagińska, E., Majchrzak, T., Młynarczyk, M., Rachoń, D., Wasik, A., & Płotka-Wasylka, J. (2024). Assessment of baby disposable diapers application for urine collection and determination of phthalate metabolites. Ecotoxicology and Environmental Safety, 272, 116033. https://doi.org/10.1016/j.ecoenv.2024.116033
Goodarzi, F., & Zendehboudi, S. (2019). A Comprehensive Review on Emulsions and Emulsion Stability in Chemical and Energy Industries. The Canadian Journal of Chemical Engineering, 97(1), 281–309. https://doi.org/10.1002/cjce.23336
Guan, Y., Cheng, F., & Pan, Z. (2019). Superwetting Polymeric Three Dimensional (3D) Porous Materials for Oil/Water Separation: A Review. Polymers, 11(5), 806. https://doi.org/10.3390/polym11050806
Hsu, C. S., & Robinson, P. R. (2019). Chemical Composition. In Petroleum Science and Technology (pp. 39–56). Springer International Publishing. https://doi.org/10.1007/978-3-030-16275-7_3
Issaka, S., Nour, A., & Yunus, R. (2015). Review on the Fundamental Aspects of Petroleum Oil Emulsions and Techniques of Demulsification. Journal of Petroleum & Environmental Biotechnology, 06(02). https://doi.org/10.4172/2157-7463.1000214
Kang, S.-H., Hong, S.-G., & Moon, J. (2017). Absorption kinetics of superabsorbent polymers (SAP) in various cement-based solutions. Cement and Concrete Research, 97, 73–83. https://doi.org/10.1016/j.cemconres.2017.03.009
Khoerunnisa, F., Nurhayati, M., Hiqmah, R. N., Hendrawan, H., Dara, F., Aziz, H. A., Sonjaya, Y., & Nasir, M. (2021). Effect of pH, temperature, and electrolytes on swelling and release behaviors of PVA/AAm/GO based hydrogel composites. 020025. https://doi.org/10.1063/5.0051817
Khoo, S. C., Phang, X. Y., Ng, C. M., Lim, K. L., Lam, S. S., & Ma, N. L. (2019). Recent technologies for treatment and recycling of used disposable baby diapers. Process Safety and Environmental Protection, 123, 116–129. https://doi.org/10.1016/j.psep.2018.12.016
Kiatkamjornwong, S. (2007). Superabsorbent Polymers and Superabsorbent Polymer Composites. ScienceAsia, 33(s1), 039. https://doi.org/10.2306/scienceasia1513-1874.2007.33(s1).039
Kokal, S. (2005). Crude-Oil Emulsions: A State-Of-The-Art Review. SPE Production & Facilities, 20(01), 5–13. https://doi.org/10.2118/77497-PA
Kotzakoulakis, K., & George, S. C. (2017). A simple and flexible correlation for predicting the viscosity of crude oils. Journal of Petroleum Science and Engineering, 158, 416–423. https://doi.org/10.1016/j.petrol.2017.08.058
Martínez-Barbosa, M. E., & Moreno-Corral, R. A. (2022). Washable, reusable and disposable medical textiles. In Medical Textiles from Natural Resources (pp. 717–765). Elsevier. https://doi.org/10.1016/B978-0-323-90479-7.00017-8
Moayyad Al-Nasra, & Batoul Alshamali. (2022). Self-sealing concrete mixed with ultra-high absorbent polymer. Global Journal of Engineering and Technology Advances, 12(3), 059–066. https://doi.org/10.30574/gjeta.2022.12.3.0159
Onojake, M., & Waka, T. (2021). Review of Oilfield Chemicals Used in Oil and Gas Industry. Asian Journal of Physical and Chemical Sciences, 8–24. https://doi.org/10.9734/ajopacs/2021/v9i230132
Raya, S. A., Saaid, I., Ahmed, A., & Umar, A. (2020). A critical review of development and demulsification mechanisms of crude oil emulsion in the petroleum industry. Journal of Petroleum Exploration and Production Technology, 10(4), 1711–1728. https://doi.org/10.1007/s13202-020-00830-7
Saad, M. A., Kamil, M., Abdurahman, N. H., Yunus, R. M., & Awad, O. I. (2019). An Overview of Recent Advances in State-of-the-Art Techniques in the Demulsification of Crude Oil Emulsions. Processes, 7(7), 470. https://doi.org/10.3390/pr7070470
Sahi, A., El Mahboub, K., Belem, T., Maqsoud, A., & Mbonimpa, M. (2019). Dewatering of Mine Tailings Slurries Using Superabsorbent Polymers (SAPs) Reclaimed from Industrial Reject of Baby Diapers: A Preliminary Study. Minerals, 9(12), 785. https://doi.org/10.3390/min9120785
Salima, B. A. (2023). HIDROGEL PADA LIMBAH POPOK SEBAGAI PUPUK: ANALISIS BIBLIOMETRIK MENGGUNAKAN VOS VIEWER TERINDEKS GOOGLE SCHOLAR. Journal of Scientech Research and Development, 5(2), 557–563. https://doi.org/10.56670/jsrd.v5i2.231
Santos, R. G., Loh, W., Bannwart, A. C., & Trevisan, O. V. (2014). An overview of heavy oil properties and its recovery and transportation methods. Brazilian Journal of Chemical Engineering, 31(3), 571–590. https://doi.org/10.1590/0104-6632.20140313s00001853
Sari, D. K., & Sauqi, N. (2020). PENGARUH DEMULSIFIER A DAN DEMULSIFIER B TERHADAP CRUDE OIL BENTAYAN DENGAN METODE BOTTLE TEST DEMULSIFIER. Jurnal Teknik Patra Akademika, 10(02), 23–30. https://doi.org/10.52506/jtpa.v10i02.91
Sousa, A. M., Pereira, M. J., & Matos, H. A. (2022). Oil-in-water and water-in-oil emulsions formation and demulsification. Journal of Petroleum Science and Engineering, 210, 110041. https://doi.org/10.1016/j.petrol.2021.110041
Struchkov, I. A., Roschin, P. V., Litvin, V. T., Ol’hovskaya, V. A., & Kalinin, E. S. (2020). Investigations of temperature and dilution effect on rheological properties of waxy crude oil. Journal of Petroleum Exploration and Production Technology, 10(2), 755–767. https://doi.org/10.1007/s13202-019-00779-2
Umar, A. A., Saaid, I. B. M., Sulaimon, A. A., & Pilus, R. B. M. (2018). A review of petroleum emulsions and recent progress on water-in-crude oil emulsions stabilized by natural surfactants and solids. Journal of Petroleum Science and Engineering, 165, 673–690. https://doi.org/10.1016/j.petrol.2018.03.014
Venkatachalam, D., & Kaliappa, S. (2023). Superabsorbent polymers: a state-of-art review on their classification, synthesis, physicochemical properties, and applications. Reviews in Chemical Engineering, 39(1), 127–171. https://doi.org/10.1515/revce-2020-0102
Wong, S. F., Lim, J. S., & Dol, S. S. (2015). Crude oil emulsion: A review on formation, classification and stability of water-in-oil emulsions. Journal of Petroleum Science and Engineering, 135, 498–504. https://doi.org/10.1016/j.petrol.2015.10.006
Yonguep, E., Kapiamba, K. F., Kabamba, K. J., & Chowdhury, M. (2022). Formation, stabilization and chemical demulsification of crude oil-in-water emulsions: A review. Petroleum Research, 7(4), 459–472. https://doi.org/10.1016/j.ptlrs.2022.01.007
Zekry, M., Nassar, I., Salim, H., & Abdallah, A. (2020). The Potential of super absorbent polymers from diaper wastes to enhance water retention properties of the soil. Soil & Environment, 39(1), 27–37. https://doi.org/10.25252/SE/2020/132058
Zhang, W., Wang, P., Liu, S., Chen, J., Chen, R., He, X., Ma, G., & Lei, Z. (2021). Factors affecting the properties of superabsorbent polymer hydrogels and methods to improve their performance: a review. Journal of Materials Science, 56(29), 16223–16242. https://doi.org/10.1007/s10853-021-06306-1
Zolfaghari, R., Fakhru’l-Razi, A., Abdullah, L. C., Elnashaie, S. S. E. H., & Pendashteh, A. (2016). Demulsification techniques of water-in-oil and oil-in-water emulsions in petroleum industry. Separation and Purification Technology, 170, 377–407. https://doi.org/10.1016/j.seppur.2016.06.026.
Downloads
Submitted
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Prayang Sunny Yulia, Aditya Yoga Pratama, Samsol Samsol, Ridha Husla, Widia Yanti

This work is licensed under a Creative Commons Attribution 4.0 International License.
Journal of Emerging Science and Engineering published under the terms of a Creative Commons Attribution 4.0 International License / CC BY 4.0 This license permits anyone to copy and redistribute this material in any form or format, compose, modify, and make derivative works of this material for any purpose, including commercial purposes, so long as they include credit to the Authors of the original work.











